English | 2021 | ASIN: B0936MVZZC | 617 pages | PDF | 5.60 MB

CONTENTS- ADVANCED PRACTICAL PHYSICAL CHEMISTRY,
Chapter 1: General Information
1.1 Calibration of Weights
1.2 Cleaning of Volumetric Glassware
1.3 Calibration of Volumetric Glassware
1.4 Concentration of Solution
1.5 Preparation of Standard Solutions
1.6 Preparation of Solutions of Indicators
1.7 Temperature Control Thermostat
Chapter 2: Errors in Measurements and Treatment of Experimental Data
2.1 Errors in Experimental Data
2.2 Accuracy and Precision of Measurements
2.3 Statistical Treatment of Random Errors
Chapter 3: Molecular Weights of Volatile Substances
3.1 Vapour Density
Chapter 4: Determination of Molecular Weights in Solution (Cryoscopic and Ebullioscopic Methods)
4.1 Introduction
4.2 Measurement of Depression of Freezing Point (Cryoscopy)
4.3 Measurement of Elevation of Boiling Point (Ebullioscopy)
4.4 Cryoscopic Methods
4.5 Rast's Micro Method of Determining Molecular Weight
4.6 Activity Coefficients of Electrolytes (Cryoscopic Method)
4.7 Ebullioscopic Methods
4.8 Suggestions for Further Work by Ebullioscopic Measurements
Chapter 5: Density of a Liquid
5.1 Introduction
5.2 Specific Volume
5.3 Molar Volume
Chapter 6: Viscosity
6.1 Introduction
6.2 Factors Affecting Viscosity of a Liquid
6.3 Molecular Viscosity
6.4 Measurement of Viscosity
Chapter 7: Surface Tension
7.1 Surface Tension
7.2 Molecular or Molar Surface Energy
7.3 Measurement of Surface Tension
Chapter 8: Vapour Pressure of Liquids
8.1 Introduction
8.2 Measurement of Vapour Pressure
Chapter 9: Solubility
9.1 Solubility
Chapter 10: Phase Equilibria
10.1 Liquid-Vapour Equilibria
10.2 Liquid-Liquid System
10.3 Study of Complex Ion Formation by Distribution Method
10.4 Solid-Liquid Systems (Freezing Point Diagrams of Binary Mixtures)
Chapter 11: Transition Temperature
11.1 Introduction
11.2 Determination of Transition Temperature
Chapter12:Thermochemistry
12.1 Introduction
12.2 Measurement of Heat Change
Chapter 13: Optical Measurements in Chemistry
13.1 Introduction
13.2 Refractometry
13.3 Polarimetry
13.4 Absorptiometry or Colorimetry
13.5 Analysis of a Mixture
13.6 Formula of the Complex (Job's Method)
13.7 Determination of Dissociation Constants
13.8 Spectrophotometric Titrations
13.9 Flame Photometry
Chapter 14: Electric Conductance of Electrolytes
14.1 Introduction
14.2 Measurement of Conductance
14.3 Applications of Conductometric Measurements
14.4 Titration of Very Weak Acids with a Strong Base
14.5 Titration of Very Weak bases with Strong Acid
14.6 Precipitation Titrations
14.7 Miscellaneous Titration
Chapters 15: Transport Numbers
15.1 Introduction
15.2 Determination of Transport Number
Chapter 16 : Chemical Kinetics
16.1 Introduction
16.2 Determination of the Order of a Reaction
16.3 Drawing Tangents to a Curve
16.4 The Temperature Coefficient (Energy of Activation)
16.5 Photochemical Reactions
Chapter 17: The Colloidal State
17.1 Introduction
17.2 Dialysis of Colloidal Solution
17.3 Precipitation of Colloids by Electrolytes
17.4 Protection of Colloids
17.5 Colloidal Electrolytes or Association Colloids
Chapter 18: Absorption
18.1 Introduction
18.2 Adsorption Isotherms
Chapter 19 : Chromatographic Separations
19.1 Chromatography
19.2 Column Chromatography
19.3 Adsorption Chromatography
19.4 Paper Chromatography
19.5 Thin-Layer Chromatography
19.6 Ion Exchange or Displacement Chromatography
19.7 Ion Exchange Capacity
19.8 Paper Electrophoresis or Zone Electrophoresis
Chapter 20: Electromotive Force of Cells
20.1 Galvanic Cells
20.5 Types of Electrodes
20.6 Indicating Electrodes
20.7 Measurement of e.m.f. of a Cell
20.8 Applications of e.m.f. Measurements
20.9 Determination of pH Values
20.10 pH Standards for Glass Electrodes at 25C
20.11 Potentiometric Titrations
20.12 Dissociation Constants of Weak Acids and Bases
20.13 Titrations without reference Electrodes
Chapter 21: Polarography
21.3 Commercial Polarograph
21.4 Decomposi
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