English | 2021 | ASIN: B093CC7KKC | 744 pages | PDF | 8.74 MB

CONTENTS- UGC PATTERN PHYSICAL CHEMISTRY-I,
Chapter-1: Introduction to Exact Quantum Mechanical Results
1. Introduction
2. Failure of Classical Mechanics
3. De-Broglie's Concept of the Dual Nature of the Electron
4. Heisenberg's Uncertainity Principle
5. Schrödinger's Wave Equations
6. Eigen Values and Eigen Functions
7. Further Mathematical Consideration of Schrödinger Equation
8. Applications of Wave Mechanics
Chapter-2: Approximate Methods
1. Introduction
2. Variation Theorem
3. Linear Variation Principle
4. The Variation Method
5. The Time-Independent Perturbation Theory
6. Nondegenerate Perturbation Theory
7. The Perturbation Method
8. Application of First-Order Perturbation Theory to Helium Atom
9. Application to Helium Non Degeneracy : The Secular Equations
10. The Valence Bond Theory
11. Formation of Hydrogen Molecule
12. Molecular Orbital Method
Chapter-3: Angular Momentum
1. Introduction to Ordinary Angular Momentum
2. Generalised Angular Momentum and Angular Momentum Operators
3. Ladder Operators
4. Eigen Functions and Eigen Values of J2 and Jz
5. Spin
6. Antisymmetry or Pauli Antisymmetry Principle
7. The Pauli Exclusion Principle
8. Addition of Angular Momentum
Chapter-4: Electronic Structure of Atom
1. Introduction
2. Electronic Configuration
3. Russell-Saunders Terms-Symbol and Coupling Schemes
4. Slater-Condon Parameters
5. Term Separation Energies of the pn Configuration and dn Configuration
6. Magnetic Effect
7. Spin Orbital Coupling
8. Zeeman Effect/Zeeman Splitting
9. Hartree and Hartree-Fock Self-Consistent Field (SCF) Method
10. Virial Theorem
Chapter-5: Molecular Orbital Theory
1. Introduction
2. Hückel Theory of Conjugated Systems
3. Electron Charge Density
4. Bond Order
5. Applications of Hückel Theory of Conjugated Systems
6. Simple Hückel Theory for the Cyclic Conjugated Systems and Aromaticity
7. Extended Hückel Theory (EHT)
Chapter-6: Chemical Thermodynamics
1. Introduction
2. Importance of Thermodynamics
3. Terminology of Thermodynamics
4. Perfect Differentials or Exact Differentials
5. Cyclic Rule
6. Simple Systems
7. Zeroth Law of Thermodynamics
8. First Law of Thermodynamics
9. Internal Energy
10. Enthalpy
11. Heat Capacity
12. Heat
13. Energy
14. Work
15. Reversible Work of Expansion (Reversibility and Maximum Work)
16. Irreversible Work of Expansion
17. Comparison of wrev and wirr
18. Work Done in Adiabatic Expansion of an Ideal Gas (Reversible Expansion)
19. Adiabatic Irreversible Expansion
20. Variation of Energy with Temperature and Volume
21. Enthalpy as a Function of T and P
22. Applications of the First Law of Thermodynamics
23. Reversible Isothermal Expansion of Real Gas Obeying van der Waals Equation
24. Reversible Adiabatic Expansion of Real Gas Obeying van der Waals Equation
25. Spontaneous Processes
26. Non-spontaneous Processes
27. Limitations of First Law of Thermodynamics- Need for the Second Law of Thermodynamics
28. Statements of Second Law of Thermodynamics
29. Thermodynamic Scale
30. Proof of the Equivalence of the Kelvin-Planck and Clausius Statements
31. Heat Engine
32. Carnot's Cycle in the Reverse Order Refrigerator
33. Carnot's Theorem
Chapter-7: Classical Thermodynamics
1. Introduction
2. Free Energy Work Functions
3. Gibbs-Helmholtz Equation
4. Thermodynamic Equilibria and Free Energy Functions
5. Applications of Gibbs-Helmholtz Equation
6. The Clapeyron-Clausius Equation
7. Thermodynamics of Elevation of Boiling Point
8. Relation between Osmotic Pressure and Elevation of Boiling Point
9. Thermodynamics of Depression in Freezing Point
10. Relation between Osmotic Pressure and Depression in Freezing Point
11. Raoult's Law
12. The Nernst Heat Theorem
13. Chemical Potential
14. Gibbs-Duhem Equation
15. Variation of Chemical Potential with Temperatur
19. The Chemical Potential of an Ideal Gas in a Mixture of Ideal Gases
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